Nyochaa: Tulee nguzogide alkali, ịsacha ụgbụ, mwepụ mmanụ na mwepụ wax arụ ọrụ dị iche iche surfactants na-adịkarị na ahịa taa, gụnyere ụdị abụọ a na-ejikarị nke nonionic na anionic.
Ndepụta nke nguzogide alkali dị iche iche surfactants
Nguzogide alkali nke surfactants nwere akụkụ abụọ. N'otu aka ahụ, ọ bụ nkwụsi ike nke usoro kemịkalụ, nke a na-egosipụtakarị site na mbibi nke mkpụrụ ndụ hydrophilic site na alkali siri ike; N'aka nke ọzọ, ọ bụ nkwụsi ike nke aggregation steeti na aqueous mmiri mmiri, nke tumadi pụtara site nnu mmetụta na-ebibi ihe mgbaze nke surfactant na-eme surfactant ise n'elu ma ọ bụ sink na iche na mmiri.
Usoro ule: Were 10g/L nke surfactant, tinye flake alkali, tinye ya na okpomọkụ a kapịrị ọnụ maka nkeji 120 wee hụ, ọnụọgụ alkali mgbe delamination ma ọ bụ ịcha mmanụ na-eme bụ nkwụsị alkali kachasị.
Tebụl na-esonụ na-egosi nguzogide alkali nke ndị surfactants nkịtị dị ugbu a.
| Aha nke surfactant | 40 ℃ | 70 ℃ | 100 ℃ |
| AEO-5 | Sodium hydroxide 15 g/l | Sodium hydroxide 13 g/l | Sodium hydroxide 3g/l |
| AEO-7 | Sodium hydroxide 22 g/l | Sodium hydroxide 14 g/l | Sodium hydroxide 5g/l |
| AEO-9 | Sodium hydroxide 30 g / l | Sodium hydroxide 24 g/l | Sodium hydroxide 12 g / l |
| TX-10 | Sodium hydroxide 19 g/l | Sodium hydroxide 15 g/l | Sodium hydroxide 6g/l |
| OP-10 | Sodium hydroxide 27 g/l | Sodium hydroxide 22 g/l | Sodium hydroxide 11 g/l |
| Onye nnọchi anya JFC | Sodium hydroxide 21 g/l | Sodium hydroxide 16 g/l | Sodium hydroxide 9g/l |
| Ngwa ngwa T banye | Sodium hydroxide 10 g / l | Sodium hydroxide 7 g/l | Sodium hydroxide 3g/l |
| Netwọk ncha 209 | Sodium hydroxide 18 g/l | Sodium hydroxide 13 g/l | Sodium hydroxide 5g/l |
| EL-80 | Sodium hydroxide 29 g/l | Sodium hydroxide 22 g/l | Sodium hydroxide 8 g/l |
| Abụọ 80 | Sodium hydroxide 22 g/l | Sodium hydroxide 11 g/l | Sodium hydroxide 7 g/l |
| Ogologo oge 80 | Sodium hydroxide 14 g/l | Sodium hydroxide 13 g/l | Sodium hydroxide 5 g/l |
| Sodium dodecylbenzene sulfonate LAS | Sodium hydroxide 24 g/l | Sodium hydroxide 16 g/l | Sodium hydroxide 9g/l |
| Sodium dodecyl sulfate SDS | Sodium hydroxide 81 g/l | Sodium hydroxide 44 g/l | Sodium hydroxide 15 g / l |
| Sodium secondary alkyl sulfonate SAS | Sodium hydroxide 30 g / l | Sodium hydroxide 22 g/l | Sodium hydroxide 12 g / l |
| Sodium decyl-sulfonate AOS | Sodium hydroxide 29 g/l | Sodium hydroxide 20 g/l | Sodium hydroxide 13 g/l |
| Aki oyibo acid diethanolamide | Sodium hydroxide 18 g/l | Sodium hydroxide 8 g/l | Sodium hydroxide 3 g/l |
| Ihe ọṅụṅụ mmanya ether sulfate AES | Sodium hydroxide 98 g/L | Sodium hydroxide77 g/l | Sodium hydroxide 35 g / l |
| Ihe ọṅụṅụ mmanya ether carboxylate AEC | Sodium hydroxide 111 g / l | Sodium hydroxide79 g/L | Sodium hydroxide 40 g / l |
| Clotrimazole (mmiri) | Sodium hydroxide 145 g / l | Sodium hydroxide 95 g/l | Sodium hydroxide 60 g / l |
| Phosphate nke mmanya na-egbu egbu | Sodium hydroxide 180 g / l | Sodium hydroxide 135 g / l | Sodium hydroxide 110 g / l |
| Phosphate esters nke mmanya ethers nwere abụba | Sodium hydroxide 210 g / L | Sodium hydroxide 147 g / l | Sodium hydroxide 170 g / l |
Ndepụta nke arụmọrụ ịsa net surfactant
N'iji otu akụrụngwa, dị ka ọkọlọtọ mba GB13174-2003 maka nchacha akwa akwa, nwalee nhicha nhicha nke akụrụngwa dị iche iche dị ka ndị a: kwadebe akụrụngwa na mmiri siri ike 250ppm iji nweta 15% ngwọta nke ntinye ihe akụrụngwa. , na-asa ahụ dị ka GB/T 13174-2003 "Ụzọ ule ịsacha ihe mgbochi", tụọ ịdị ọcha nke akwa dị iche iche nwere ntụpọ tupu na mgbe ịsachara, wee gbakọọ uru nchekwa R dị ka usoro a:
R(%)=F2-F1
Ebe F1 bụ uru ọcha tupu akwọchaa nke akwa meruru emeru (%), F2 bụ uru ọcha gachara nke akwa emetọọ (%).
Ka uru R buru ibu, ka ikike ịsa ụgbụ na-esiwanye ike. Enwere ike iji ọkọlọtọ ule a gosipụta mwepụ nke unyi n'ozuzu site na surfactants na ọ bụghị na ọdabara iji gosipụta ikike mwepụ nke griiz na wax.
| Aha nke surfactant | R (%) uru |
| AEO-3 | R (%) = 3.69 |
| AEO-5 | R (%) = 3.31 |
| AEO-7 | R (%) = 9.50 |
| AEO-9 | R (%) = 12.19 |
| TX-10 | R (%) = 15.77 |
| NP-8.6 | R (%) = 14.98 |
| OP-10 | R (%) = 14.55 |
| XL-90 | R (%) = 13.91 |
| XP-90 | R (%) = 4.30 |
| TO-90 | R (%) = 15.58 |
| Onye njikwa JFC | R (%) = 2.01 |
| Ngwa ngwa T banye | R (%) = 0.77 |
| Netwọk ncha 209 | R (%) = 4.98 |
| Sodium dodecylbenzene sulfonate LAS | R (%) = 9.12 |
| Sodium dodecyl sulfate SDS | R (%) = 5.30 |
| Sodium decyl-sulfonate AOS | R (%) = 8.63 |
| Sodium secondary alkyl sulfonate SAS | R (%) = 15.81 |
| Ihe ọṅụṅụ mmanya ether sulfate AES | R (%) = 5.91 |
| Ihe ọṅụṅụ mmanya ether carboxylate AEC | R (%) = 6.20 |
| Clotrimazole (mmiri) | R (%) = 15.55 |
| Phosphate nke mmanya na-egbu egbu | R (%) = 2.08 |
| Phosphate esters nke mmanya ethers na-egbu egbu AEP | R (%) = 5.88 |
Ntụle nke mkpochapụ mmanụ arụmọrụ nke dị iche iche surfactants
A na-eme nnwale mwepụ mmanụ nke surfactant (usoro mwepụ mmanụ) dị ka GB 9985-2000 Appendix B si dị, na-eji ncha ọkọlọtọ dị ka usoro ọkọlọtọ. Gbakọọ ọnụego mwepụ mmanụ (C) dịka usoro a si dị:
C = mma mwepu mmanụ nke ihe nlele / mwepu mmanụ nke ụkpụrụ ọkọlọtọ
Ka uru C buru ibu, ka ikike iwepụ mmanụ nke surfactant na-esiwanye ike
| Aha nke surfactant | De-oiling C uru |
| AEO-3 | Uru De-mmanụ C = 1.53 |
| AEO-5 | Uru De-mmanụ C = 1.40 |
| AEO-7 | Uru De-mmanụ C = 1.22 |
| AEO-9 | Uru De-mmanụ C = 1.01 |
| TX-10 | Uru De-mmanụ C = 1.17 |
| NP-8.6 | Uru De-mmanụ C = 1.25 |
| OP-10 | Uru De-mmanụ C = 1.37 |
| XL-90 | Uru De-mmanụ C = 1.10 |
| XP-90 | De-oiling C uru = 0.66 |
| TO-90 | Uru De-mmanụ C = 1.40 |
| Banye JFC | De-oiling C uru = 0.77 |
| Fatty acid methyl ester ethoxylate FMEE | Uru De-mmanụ C = 1.94 |
| Ngwa ngwa T banye | De-oiling C uru = 0.35 |
| Netwọk ncha 209 | De-oiling C uru = 0.76 |
| Sodium dodecylbenzene sulfonate LAS | De-oiling C uru = 0.92 |
| Sodium dodecyl sulfate SDS | De-oiling C uru = 0.81 |
| Sodium decyl-sulfonate - AOS | De-oiling C uru = 0.73 |
| Sodium secondary alkyl sulfonate SAS | De-oiling C uru = 0.98 |
| Ihe ọṅụṅụ mmanya ether sulfate AES | De-oiling C uru = 0.63 |
| Ihe ọṅụṅụ mmanya ether carboxylate AEC | De-oiling C uru = 0.72 |
| Clotrimazole (mmiri) | De-mmanụ C uru = 1.11 |
| Phosphate nke mmanya na-egbu egbu | Nri mmanụ C = 0.32 |
| Phosphate esters nke mmanya ethers na-egbu egbu AEP | De-oiling C uru = 0.46 |
Surfactant waks iwepụ arụmọrụ ntụnyere tebụl
1. Nkwadebe nke ọkọlọtọ wax akwa ákwà
Gbanyụọ ngọngọ wax ọkọlọtọ na ogo 90 nke mmiri ọkụ, kpalie nke ọma wee tinye ya n'ime akwa akwa akwa ọcha na-acha ọcha, wepụ ya mgbe nkeji abụọ gachara wee kpoo ikuku.
2. Usoro ule
A na-egbutu akwa wax n'ime 5 * 5cm, na-emikpu n'ime mmiri na-arụ ọrụ na ntinye 5% nke akụrụngwa, na-asa ya site na oscillation maka nkeji 10 n'okpuru ọnọdụ okpomọkụ nke 100 degrees, na-asa ya na mmiri oyi zuru oke, na-acha ọcha nke a na-asacha. A na-atụ akwa akwa wax, na ka uru na-acha ọcha W bụ, otú ahụ ka mma iwepụ ikike nke surfactant dị mma.
| Aha nke surfactant | W uru |
| AEO-3 | W=67.42 |
| AEO-5 | W=61.98 |
| AEO-7 | W=53.25 |
| AEO-9 | W=47.30 |
| TX-10 | W=46.11 |
| NP-8.6 | W=60.03 |
| OP-10 | W=58.92 |
| XL-90 | W=48.54 |
| XP-90 | W=33.16 |
| TO-7 | W=68.96 |
| TO-9 | W=59.81 |
| Fatty acid methyl ester ethoxylate FMEE | W=77.43 |
| Triethanolamine | W=49.79 |
| Triethanolamine oleic ncha | W=56.31 |
| Netwọk nhicha 6501 | W=32.78 |
| Banye JFC | W=31.91 |
| Ngwa ngwa T banye | W=18.90 |
| Netwọk ncha 209 | W=22.55 |
| Sodium dodecylbenzene sulfonate LAS | W=34.17 |
| Sodium dodecyl sulfate SDS | W=27.31 |
| Sodium decyl-sulfonate - AOS | W=29.25 |
| Sodium secondary alkyl sulfonate SAS | W=30.87 |
| Ihe ọṅụṅụ mmanya ether sulfate AES | W=26.37 |
| Ihe ọṅụṅụ mmanya ether carboxylate AEC | W=33.88 |
| Clotrimazole (mmiri) | W=49.35 |
| Phosphate nke mmanya na-egbu egbu | W=20.47 |
| Phosphate esters nke mmanya ethers na-egbu egbu AEP | W=29.38 |
Oge nzipu: Mar-03-2022