Isiokwu dị na edemede a:
1. Mmepe nke amino acid
2. Njirimara Njirimara
3. Ihe mejupụtara kemịkalụ
4.cilification
5. Synthesis
6. Njirimara Phyctochemical
7. Na-egbu egbu
8. Ọrụ antimicrobial
9. Njirimara nke Rhioloul
10. Ngwa na ụlọ ọrụ ịchọ mma
11. Ngwa na-agakwa
Amino acid Sourt (AAS)bụ klas nke sustocts guzobere site na ijikọta otu acdrophobic na otu ma ọ bụ karịa amino acid. N'okwu a, Amino acid nwere ike ịbụ synetik ma ọ bụ sitere na protein hydrolly ma ọ bụ isi mmalite yiri nke ahụ. Akwụkwọ a na-ekpuchi nkọwa nke ọtụtụ ụzọ dị iche iche maka AAS na mmetụta nke ụzọ dị iche iche na phytochemical Njirimara nke ngwaahịa ọgwụ, gụnyere ịdọ aka, nkwụsị na biodegradity. Dị ka klaasị nke sustonts na-abawanye, ma ọ bụrụ nke AAS n'ihi nhazi usoro ha na-enye ọtụtụ ohere azụmahịa ha.
Nyere na a na-ejikarị ya sọlfọ na-eme ọtụtụ ihe n'ọtụtụ ebe, ndị iro na-egbochi ha, ndị na-eme nchọpụta akwụsịbeghị ị paya ntị na Surractants.
Ndị na-eme ihe nkiri bụ ihe nnọchi anya kemịkalụ nke a na-ere na nnukwu ihe kwa ụbọchị gburugburu ụwa ma nwee mmetụta na-adịghị mma na gburugburu ebe obibi.Nnyocha e mere egosila na ojiji eji supersacket Surfal nwere ike inwe mmetụta na-adịghị mma na gburugburu ebe obibi.
Taa, ihe na-adịghị egbu egbu, biodegrabity na biocompatibility dị mkpa maka ndị na-azụ ahịa dị ka ịba uru na ịrụ ọrụ nke South.
Ndị na - eme biosturfacents bụ ihe na - adịkarị mma nke na - eme ihe na - enweghị usoro dị ka nje bacteria, dịkwa ka ndị na - e yie yie.Ya mere, enwere ike ịkwadebe biosfulatints site na ihe eji eme ihe na -eme ihe omimi ampalilic, dị ka phospholipids, alkyl glycosides na Ac Acy Acs.
Amino acid Sourt (AAS)bụ otu n'ime ndị na-ahụkarị, na-emepụtakarị site na anụmanụ ma ọ bụ ọrụ akọ na ụba. N'ime afọ iri abụọ gara aga, AAS dọtara nnukwu mmasị site na ndị ọkà mmụta sayensị dị ukwuu, ọ bụghị naanị n'ihi na ha nwere ike imebi ya, na-eme ka ha dị nchebe maka gburugburu ebe obibi.
Enwere ike ịkọwa AAS dị ka klaasị nke Surfacts nke nwere Amino acid nwere ọdịdị Amino (ho 2 c-ch 2) ma ọ bụ amino acid acid (ho 2 c-ser-nh-). Mpaghara 2 arụ ọrụ Amino acid na-enye ohere maka njupụta nke ụdị dịgasị iche iche. Ngụkọta nke Amino Amino Aminogenic 20 proocounogenic 20 na-adị na okike ma na-ahụ maka mmeghachi omume niile na uto na ndụ. Ha dị iche na ibe ha naanị dị ka ebe a na-edebe mmiri r (Figure 1, PK a bụ Bagerithm na-adịghị mma nke acand constantiilation mgbe niile). Somefọdụ bụ polar na hydrophobic, ụfọdụ na-akụ polar na hydrophilic, ụfọdụ bụ isi na ụfọdụ bụ acidic.
N'ihi Amino acid na-eme mgbanwe, Surractants Ndepụta si Amino acid na-enwe ike ịkwado na gburugburu ebe obibi. Ọdịdị dị mfe na ebumpụta ụwa, na obere ihe na-egbu egbu na ngwa ngwa na-eme ka ha dị elu karịa ka ndị na-eme mkpọtụ. N'iji ihe eji eme mmanu (dika amino acid na mmanu akwukwo nri), apuru iji uzo ihe omumu di iche iche.
Na mbido narị afọ nke 20, a chọpụtara amino acids ka ọ bụrụ nke a na-eji eme ihe maka njikọta ihu.A na-ejikarị AAS dị ka nchekwa na usoro ọgwụgwọ ọgwụ.Na mgbakwunye, a hụrụ AAS na-arụsi ọrụ ike megide ọtụtụ ọrịa na-akpata ọrịa, okwute na nje. N'afọ 1988, nnweta nke dị ala nke AAS na-enweghị mmasị na nyocha nyocha na ebe a na-eme ihe. Taa, site na mmepe nke bionology, ụfọdụ amino acids na-enwekwa ike ijikọ azụmahịa n'ahịa azụ site na yist, nke na-egosi na mmepụta AAS na-egosipụta ebe obibi.
01 mmepe nke amino acid
Dị ka mbido narị afọ nke 19, a na-ebu ụzọ chọpụta Amino acid na mbụ, a na-ebu ụzọ buru ihe owuwu ha dị oke mkpa - iji akụrụngwa maka nkwadebe Ampilles. Ọmụmụ ihe mbụ na njikọta nke AASI na 1909.
N'ime ọmụmụ ihe ahụ, n-acyyylycine na n-Acylalanine dị ka otu hydrophilic dị iche iche maka Sustorants. Ọrụ ndị na-esote metụtara njikọta nke Lipoamiasimlo acid (AAS) site na iji Glycine na alanine, na hentrich et al. Bipụtara usoro nchọta,Gụnyere ngwa mgbakwunye mbụ, na iji acyl acarpate na acyl acpartents na ngwaahịa nhicha ụlọ (dịka Shampoos, na-egbochi ya na eze.Nke a bụ, ọtụtụ ndị nyocha nyocha nyochachara njikọ na akụrụngwa Acy Acy. Ruo taa, ebipụta nnukwu akwụkwọ e bipụtara na njikọ, Njirimara, ngwa ụlọ ọrụ na biodegrad ngwa nke AAS.
02 Njirimara Njirimara
Ahịhịa amị amị amị acid nke AAS nwere ike ịdị iche na nhazi, eriri ogologo na ọnụ ọgụgụ.Ọdịdị dị iche iche na-arụ ọrụ na nnukwu ọrụ nke Aas na-akọwa ọdịiche dị iche iche na ihe ọmụmụ na ihe ndị dị ndụ. Ndị isi otu nke aas mejupụtara amino acid ma ọ bụ peptide. Ọdịiche dị na òtù dị iche iche na-ekpebi mgbasa ozi, nchịkọta na ọrụ ndu nke Sellow. Otu ndị ọrụ dị na isi ahụ na-ekpebi ụdị AAS, gụnyere cadic, anaonic, na amphotic. Nchikota Acy acids acids na hydrophobic n'ogologo ya na-etolite ihe owuwu amppalilic nke na-eme ka molekulu dị elu nke ukwuu. Na mgbakwunye, ọnụnọ Asymmetric carbon atọm na-enyere aka ịghọ ụmụ irighiri chiral.
03 kemịkal
Freptides niile na poly rostodes bụ ngwaahịa polymerization nke ndị a fọrọ nke nta ka ọ bụrụ 20 α-proteinogenic α-amino acid. Acy 20 α-amino nwere carks acid ọrụ (-coh) na otu ọrụ amino (-nh 2), ha abụọ na-eso na otu tetrazedral α-carbon. Amino acids dị iche na nke ọ bụla ọzọ site na ndị otu dị iche iche jikọtara ya na α-carbon (nke Rù bụ hyrogen nwere ike ịdị iche na nhazi, nha na ụgwọ (acidity, alkality). Ọdịiche ndị a na-ekpebikwa ngelite nke amino acid na mmiri.
Amino acid bụ chiral (belụsọ maka Glycine) ma na-arụ ọrụ site na okike n'ihi na ha nwere njikọ anọ dị iche iche na Alfa Carbo. Amino acid nwere mmekorita abuo; Ha bụ ihe oyiyi enyo na-abụghị nke ọzọ, n'agbanyeghị eziokwu ahụ bụ na ọnụ ọgụgụ L-Sheroisomers dị elu karịa. Ndị otu R-otu nọ na ụfọdụ amino acid (Phenylalanine, ndị isi na tryptophan) bụ arl, na-eduga na nnabata uv kachasị na 280 NM. Acidic α-cooh na nke nkiti α-NH 2 na Amino acid nwere ike ionization, ma ndi obula ha bu, na-ewu uzo iontibrium egosi n'okpuru.
R-cooh ↔r-coo- -+ H+
R-nh3+↔r-nh2+ H+
Dị ka egosiri na usoro ionization dị n'elu, amino acts nwere opekata mpe abụọ na-adịghị ike; Agbanyeghị, otu na-ahụkarị ụgbọ ala bụ acidic ka e ji atụnyere ndị otu Amino. PH 7.4, otu carnetyl na-egbochi ebe a na-etinye Amino. Amino acid na-abụghị nke na-abụghị nke ikuku bụ iche iche na plọ ọrụ plọ a ma mepụta Zwitterion.
Ọdịdị 04
Enwere ike ịhazi AAS dị ka njiri mara anọ, nke akọwara n'okpuru n'okpuru.
4.1 Dika esi bia
| Dabere na mbido, a ga-ekewa AAS ụzọ abụọ dị ka ndị a. ① Atiory eke Somefọdụ na-eme ka acid nwere Amino acid nwekwara ikike iji belata esemokwu dị elu / interfacial, ma ụfọdụ gafere arụmọrụ nke glycolipids. A na-amarakwa Aas dị ka LOPOPEptidedes. Lpopoptides bụ ihe dị arọ molecular dị arọ, nke anụ ezi.
A na-ekewa nke a na subclasses atọ:Surftacin, ITURIN na Fengycin.
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| Ezinaụlọ nke ndị na-eme ka ihe ndị dị elu na-eme ka ihe dịgasị iche iche nke ihe dịgasị iche iche,Dịka egosiri na eserese 2a, nke C16-c16 na-enweghị atụ acid acid β-hydroxy tiye na peptide. Oke peptide nọ n'ọrụ bụ Macrocyclic Lactone nke mgbanaka na-emechi site na cariri na captinos nke β-hydroxy abụba acid na peptide. N'ime subCluin nke Iturin, enwere isi isii, ya bụ ITURIN A na C, MyCosibtilin na Bacillilycin D, F na L.N'okwu niile, a na-ejikọ nkụ ahụ na eriri C14 nke abụba nke C14 nke abụba acid (agbụ ndị nwere ike ịdị iche). N'ihe banyere Ekurimycins, ndị otu amino nọ na Β-ọnọdụ nwere ike ịmalitekọ na-eji si otú a na-akpụ ahịhịa macrocyclic.
E nwere Frowclas nwere Fengycin A na b, nke a na-akpọ pịpastatin mgbe tyr9 ka edobere.A na-ejikọ eriri ahụ na C14 -c18 jupụtara ma ọ bụ na-enweghị atụ acid acid. Usoro, plipastatin bụkwa macrocyclic lactone, nwere tip akụkụ nke peptidue na-akpụzi ihe owuwu (dị ka ọ bụ maka ọtụtụ Lọdomonas Lipotomas).
② Astiber AAS nwekwara ike ijikọ site na iji nke ọ bụla acidic, bụ nke bụ amino acid. Amino acid a na-eji acid nke acid na-eji maka njikọta nke aas bụ acid nke as bụ acid acid, proinine proline, glycine, ọnya afọ, na protein hydroys. Enwere ike ịkwadebe surclass a site na kemịkal, enzymatic, na usoro kemmozonmatic; Agbanyeghị, maka mmepụta nke AAS, kemịkal na-ekwekọ. Ihe atụ ndị a na-ahụkarị gụnyere N-Lauroyl-L-Glutamic acid na N-Palmiteyl-L-Glutamic acid.
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4.2 Dabere na ndị na-eme ihe
E nwere ike kewaa ihe ndị dị na Aliphatic Fint, Amino acid-dabeere na ụdị 2.
Dabere na ọnọdụ nke onye rụrụ arụ
| AAS N'ime ogige n-a na-eji dochie anya, otu lipophilic otu dochie ma ọ bụ otu na-elekọta ebugharị, na-ebute ọnwụ. Ihe atụ dị mfe nke n-dochie anya AAS bụ n-acyy amino acid, nke bụ nke bụnic. N-dochie anya AAS nwere njikọ dị n'etiti n'etiti hydrophobic na hydrophilic. Njikọ ncheta nwere ike ịhazi nkekọ hydrogen, nke na-eme ka nrụrụ nke nke a na-agba gburugburu gburugburu ebe a na-aghọ ihe acidic, si otú a na-eme ya biodegradable.
②c-iji ya Na ogige a na-eji dochie anya, ihe eji dochie anya na otu carboxy n'otu (site na njikọta ma ọ bụ nke aesta). Conticals compounds (dịkaster ma ọ bụ ebe obibi) bụ nke enweghị isi.
③- na c- dochie anya N'ime ụdị a, ma amino na carnety dị n'otu bụ akụkụ hydrophilic. Typedị a bụ ezigbo amphoteric soft. |
4.3 Dabere na ọnụọgụ nke ọdụ hydrophobic
Dabere na ọnụọgụ nke otu na ọdụ ọdụ hdrophobic, a ga-ekewa AAS ụzọ anọ. AAS, Gemini (Diser) ụdị AAS, Glycelipid ụdị AAS, na bicifilic Amphilic (Bola). Ahịhịa kwụ ọtọ na-asachasị ihe ndị mejupụtara amino acid site na ọdụdụ hydrophobic (ọgụgụ 3). Gemini dị iche iche nwere otu isi aciano acid abụọ na ọdụ abụọ hydrophobic abụọ kwa molekule (ọgụgụ 4). N'ime ụdị ihe owuwu a, AAs abụọ ahụ na-ejikọ ọnụ site na spacer ma na-akpọkwa ebe. Na Glycecipid ụdị AAS, n'aka nke ọzọ, ọdụ hydrophobic na-etinye otu isi amino. Enwere ike ịtụle ndị a dị ka analogy nke monaglycerides, digincerides na phospholipids, ebe a na-ejikọ otu aas, ọdụm abụọ amdrophobic.
4.4 Dị ka ụdị isi
①Cagic AAS
Ndị isi otu ụdị nke Surctant nwere ezigbo ụgwọ. Eas Cadic AAS bụ ethylo Copoyl na-ege ntị, nke bụ parrolidone carroxylate. Ngwongwo pụrụ iche na iche iche na-eme ka ọ baa uru na ọgwụ, ndị ọrụ ọgwụ mgbochi, ndị na-eme ihe na-adị nro n'anya na anụahụ na ngwa ngwa. Singare na MHATRE Sinsonized Sinsonine-Dabere na nke Cadic nke sitere na Njirimara ahụ ha. N'ime ọmụmụ ihe a, ha kwuru na ngwaahịa ndị a na-enweta site na iji ọnọdụ mmeghachi omume Smemann. A na-ahụwanye ogologo alkyly ogologo na hydrophobisicity, a hụrụ elu ọrụ dị elu iji mụbaa na ịta ahụhụ Micalet (cmc) belata. Ọzọ nke bụ protein acynalite, nke a na-ejikarị ya dị ka ihe mkpuchi na ngwaahịa nlekọta ntutu.
Eaninic
Nanic soroctants, polar isi nke sustont nwere ebubo na-adịghị mma. Sarcosine (ch 3-ch-ch 2-ch-Methyllycine), amino amylglycine), amino am na-ahụkarị na ugorchins na kpakpando n'oké osimiri, bụ ihe metụtara kemịkal nke Glycine (amcoh acid nke dị na sel mammalian. -COH,) bụ ihe metụtara kemịkal na Glycine, nke bụ a amino acid nke dị na mkpụrụ ndụ Mammalian. A na-ejikarị Lauric acid, a na-ejikarị ha na ha na-eme ihe na ebe obibi ha. A na-ejikarị nwayọọ nwayọọ nwayọọ na-ejikarị ọnụ, shampoos, fesacha aji ụfụfụ, anwụ na-acha, ngwaahịa na ngwaahịa ịchọ mma ndị ọzọ.
AASANCENCANY AAS gụnyere Amisoroft CS-22 na Amilitegckkk-12, nke bụ aha azụmahịa maka sodium n-glutanate na potassium n-copoyl glycinate, n'otu n'otu. A na-ejikarị Amamite dị ka ihe na-atọ ụtọ, ihe mgbochi, akwara, ncha, na-ehicha ncha, na-asachapụ ndị na-asa ahụ na ụlọ. A na-eji Amisoft dị ka akpụkpọ ahụ dị nro na nhicha ntutu, tumadi na ihu na ahụ dị ọcha, ihe mgbapụta synụm, ngwaahịa nlekọta anụ ahụ, shampoos na ngwaahịa nlekọta anụ ahụ.
③Zwrietic ma ọ bụ ampphineric AAS
Amphodic sara anya nwere saịtị acidic na nke nkiti ma nwee ike igbanwe ebubo ha site na igbanwe uru ph. Na Alkaline mgbasa ozi dị ka anionic Surractants, ebe gburugburu acidic ha na-akpa àgwà dị ka cradic sara mbara na mgbasa ozi dị ka amphotic na-adịghị mma. Lauryl Lysine (LL) na alkoxy (2-hydroxyyl) Argwenic bụ naanị a maara amphotic na-ama ama site na amino acid. LL bụ ihe mgbochi ngwaahịa nke Lysine na Lauric acid. N'ihi usoro ampphiteric ya, ly na-enweghị ntụpọ n'ihe fọrọ nke nta ka ọ bụrụ ụdị mgbaze niile, belụsọ maka mma alkaline ma ọ bụ ihe ndozi actic. Dị ka ntụ ntụ ahụ, ll nwere adres dị mma na mbara ihu na ala dị ala nke esemokwu dị mma, na-enye ikike a na-ahụkarị. A na-eji ọtụtụ ebe na ude anụ ahụ na ntutu isi, a na-ejikwa ya dị ka nke lubricant.
④nonionic AAS
Ndị na-abụghị ndị nnọkọ polar na-egosipụta òtù polar na-enweghị ụgwọ akwụghị ụgwọ. Al-M-Sabaght Et na-akwadokarị ya. site na mmanu-soluble α-amino acts. Na usoro a, a na-ebu ụzọ na L-viecine na-ebu ụzọ kpuchie ya na hexadecanol, na-esochi ya na palmitic acid inye palmic abụọ na ala abụọ nke α-amino acid. Ndị na-ede ihe na Esta na-emegharị anya na Etlene Oxide iji kwadebe ihe iri atọ na ọnụ ọgụgụ dị iche iche nke nkeji polyoxyeth (40, 60 na 100). Achọpụtara AASE AA ka ha nwere ezigbo ihe mgbochi na ihe na-atọ ụtọ.
05 njikọta
5.1 Onu ogugu Synthetic
Na AAS, enwere ike itinye hydrophobic otu na AMIN ma ọ bụ nke saịtị acid ma ọ bụ nke na-elekọta akụkụ nke amino acid. Dabere na nke a, ụzọ usoro Synthetic anọ dị, dị ka egosiri na eserese 5.
Fig.5 = Mkparịta ụka Amino Acid-Dabere na
| Ụzọ 1. A na-emepụta mmeghachi omume Est na-emepụta, ebe a na-emekarị njikọta ihu igwe na-enwekarị mmanya na amino acid na ọnụnọ acidic. N'ụfọdụ mmeghachi omume, sọlfọ acid actine na-eme dị ka ihe na-eme ka ọ bụrụ onye na-eme ihe nkiri.
Ụzọ 2. Acia acid na-emegharị na alkyyolanines iji mepụta avide agbụ, na-ebute njikọta nke Amidines Amphilic.
Ụzọ 3. Acid acids na-ejikọ ọnụ site na imeghachi ụdị amine amino acid na Amido acid.
Ụzọ 4. Acù Acid Acid dị ogologo na-agagharị site na mmeghachi omume nke ndị otu ụdị amone na haloalkanes. |
5.2 Ọzụzụ na Sonsonisis na Mmepụta
5.2.1 Synshesis nke otu-yeno acid / peptide Surractants
N-Acyl ma ọ bụ OCy Acid ma ọ bụ peptino acid site na acylalized acline nke amine ma ọ bụ otu hydroxy nwere abụba abụba. Nkwupụta mbụ na usoro na-akwụghị ụgwọ na-enweghị nkọ nke Amino acid ma ọ bụ methyl ester na-eji candivatives na-eji 25% na-adabere na Amino acid acid. Ejirila Methyl etyl ketone ke mmeghachi omume ụfọdụ. Vonderhagen et al. Akọwapụtala Liprase na mmeghachi omume N-Acylation nke Amino acid, protein hydroys na / ma ọ bụ ihe omimi ha site na iji ngwakọta nke mmiri (dịka, mmiri Deethyllide / Mmiri) na methyl.
N'oge izizi, isi nsogbu na Syzyme-Calisezed Synhesis nke AAS bụ ihe dị ala. Dabere na VALIVETT ET al. Mkpụrụ nke N-Tetradecanoyl Am Acid Divivatives bụ naanị 2% -10% na-eji egbugbere ọnụ dị iche iche na ịmịcha na 70 ° C ọtụtụ ụbọchị. Montet et al. Ọzọkwa na-ezute nsogbu banyere mkpụrụ amino acid na njikọ nke n-Acyl Lysine na-eji abụba abụba na mmanụ ihe oriri. Dabere na ha, mkpụrụ kachasị nke ngwaahịa ahụ bụ 19% n'okpuru ihe mgbatị ahụ na-enweghị ọnọdụ na iji sosganic sochirinụ. A na-ahụ otu nsogbu ahụ site na Valivety et al. Na njikọta nke n-cbz-l-lyline ma ọ bụ n-cbz-Lyline methy Ester ester.
N'ime ọmụmụ ihe a, ha na-ekwu na mkpụrụ nke 3-o-tetradecanoyl-l-serine bụ serine na-echedo na Novozyme 435 dị ka ihe nkiri na-eme ka ọ dị na gburugburu ebe obibi. Nagao na Kito gụrụ ihe acline, L-homoserine, a na-enweta ya na ihe a na-eme na L-homoserine na l-homoserine dị obere, ebe enweghị Aclination nke l-nocheonine ka mere.
Ọtụtụ ndị na-eme nchọpụta akwadowo ojiji nke ọnụ ọgụgụ dị ọnụ ma ngwa ngwa dị mfe maka njikọta ọnụ dị ọnụ ahịa. Soo et al. Na-ekwu na nkwadebe nke nkwụ na-arụ ọrụ na-arụ ọrụ mma na Lipozobme. Ha kwuru na mkpụrụ nke ngwaahịa ahụ ga-aka mma n'agbanyeghị oge na-eri oge (ụbọchị 6). Cevat Et al. Nyochaa njikọ ahụ na elu ọrụ nke chiral n - Palmiteyl dabere na metonine, ọnya afọ, pedylalanine na phenylglycine na cyclic / datf ngwakọta. Pang na chuno kọwara njikọ nke Amino acid dabere na monomoxy acid dabere na ndị na-arụ ọrụ na-arụ ọrụ na ebe obibi Poodeed-Dabere na nke ụlọ ọrụ na-arụ ọrụ na ngwọta.
Cantreeuuubezene na Guerreiro kọrọ na a na-ere ahịa nke Broc-ASPLOMETANE dị ka onye na-a woohụ na afọ iri anọ na anọ. N'ime ọmụmụ ihe a, mmeghachi omume nke BOC-ala-oh na mmanya na-egbu egbu ruo 16 na carbons dị mma nke 63% [64]. 99.9%) na mkpụrụ osisi sitere na 58% ruo 76%, nke a na-ejikọ ọnụ site na alkyyolines dị elu site na CBZ-Arc-Artin, ebe Papaiin mere ihe dị ka onye na-eme ihe nkiri.
5.2.2 Synshesis nke amino acid / peptide Surcectants
Amino acid-Dabere na gemini Surfractants nwere ọtụtụ ụmụ irighiri akwara aas jikọtara ọnụ na-isi na ibe ya. Enwere atụmatụ 2 nwere ike ị nwere ike isi maka njikọta chemozonMatic nke gemini acid-daturacts (ọnụ ọgụgụ 6 na 7). Na eserese 6, a na-emeghachi omume Amino acid dị ka ogige dị ka otu spacer sone na mgbe ahụ, a na-ewebata otu abụọ hydrophobic. Na eserese 7, ihe owuwu 2 kwụ ọtọ jikọtara ọnụ site na otu mpaghara spafinction.
Mmepe izizi nke njikọ enzyme-carisis na-ahụ maka gipoamiamiasim a na-asụ ụzọ ọsụ ụzọ site na Valivety erly ọsụ ụzọ. Yoshimur et al. Nyochakọta njikọta, mgbasa ozi na nchịkọta nke amino amino acid-Dabere na sustoctant dabere na cystine na n-alkyl bromide. E jiri ya tụkọta synhed na-atụnyere na ndị na-eme nyocha nke ndị ọzọ. Faustino et al. kọwara njikọ nke moonic nke moomic nke sitere na moomic Aa (Cystine, L-Cystine, L-Cystine, Equined Equium dị elu na-enweghị nsogbu na njiri mara ha. E gosipụtara ya na uru cmc nke Gemini dị ala site na iji Monomer na Gemini.
Fig.6 Synshesis nke Gemini AAS na-eji AA Medivatives na Spacer, sochiri hydrophobic otu
Fig.7 Synshesis nke Gemini nke Gemini na-eji mpaghara oghere na AAS
5.2.3 Synshesis nke glycerilipid amino acid / peptide Surractants
Glycecipid amino acid / peptides surkactacts bụ klas ọhụrụ nke Lino amino acids nke nwere otu abụba na phospholipids, n'ihi nhazi nke amino jikọtara ọnụ na-eme ka ọ bụrụ nkekọ na-agbakọta. Nchịkọta nke ndị a Sound na-amalite site na nkwadebe nke Amino acid nke Amino acid na okpomọkụ dị elu na ọnụnọ nke ihe nkiri acidic (dịka BF 3). Nchọpụta Enzyme-Calineches (na-eji hydrolases, na-eme ihe na ladis dị ka ihe na-eme ka ọ bụrụ ezigbo nhọrọ (ọgụgụ 8).
Nchọpụta enzyme-Calilezed nke Dierylated Arsoroin Glycerides na-akọ banyere papain. Nchịkọta nke DiacyLyllinlycerce Ester Esta na-akụ na nyocha nke ihe ndị ahụ Phyckomical.
Fig.8 Synshesis nke Mono na Diacylglycececercectol An Acy Conjugates
spacer: nh- (ch2)10-Nke: compoundb1
spacer: nh-c6H4-Nke: compound2
spacer: ch2-2: comporb3
Fig.9 Synshesis nke AmpMicles Amphics sitere na Tris (hydroxythyl) anwansi
5.2.4 Synshesis nke Amino Amino Acid / Peptide Surcectants
Amino amps-dabethiles ampaciles nwere 2 amino acids na-ejikọta ya na otu hydrophobic yinye. Franceschi et al. kọwara njikọ nke ampa-pịnyere Ampaliles na 2 amino acid (d- ma ọ bụ l-historine) na 1 alkyly nke ogologo dị iche iche ma nyochaa ọrụ dị iche iche. Ha kwurịtara njikọ na mkpokọta Ampa-pịnyere usoro ọmụmụ ACPACE na-eme ihe (iji ma ọ bụ na-abaghị uru americ ma ọ bụ mmanya) na mpaghara mpaghara C12 -C20. Acy acid β-amino eji nwere ike ịbụ shuga Aminomon, AZODTTMIN (AZT) Amino Acid, amino amino acid, na ọgụgụ Amino. Nchịkọta nke AmpMetrical Puness nke Ampayhical sitere na Tris (hydroxythyl) Aminomethane (TRIS) (FRIS 9).
06 Njirimara Phycochemical
A maara nke ọma na amino acid dabere na sọlfọ (AAS) dị iche iche ma nwee ezigbo emultilization, arụmọrụ dị mma, arụmọrụ dị elu na ezigbo nguzosi ike na mmiri siri ike (calcium ion na-anabata).
Dabere na Njirimara Amino Amino (dịka ihe omume dị elu dị elu, a na-ahụ maka nkwubi okwu a, a na-arụ ọrụ nkwubi okwu nke AAS dị elu karịa nke ndị otu a.
6.1 Nchọsi dị egwu Milelle (CMC)
Ntinye uche Micleration bụ otu n'ime parameta ndị dị mkpa dị ka usoro na-arụ ọrụ, na-arịwanye elu na-eme ka mbelata nke cmC uru nke ihe ngwọta, si otú a na-amụba elu ọrụ ya. Surfracts dabere na amino acid na-enwekarị ụdị CMC na-atụnyere maka ndị na-eme mkpọtụ.
Site na njikọta dị iche iche nke otu isi na ọdụ ọdụ mmiri hydrophobic (Caration Emide, Emic bi-cedic na-anọ na-anọghị na ya), nwa etemeete biden al. Synsed na Aas As ASA ma mụọ CMC na γcmc (elu esemokwu na CMC), na-egosi na ụkpụrụ CMC na γcmc na-a ịba ụba ọdụdụ hdrophobic. N'ọmụmụ ihe ọzọ, Barlare na MHATRE chọpụtara na CMC nke N-α-acylarginene ndị na-agbadata na ịba ụba nke hydrophobic ọdụm (Isiokwu 1).
Yoshimur et al. Nyochaa CMC nke Cysteine-nwetara Amino Amino acid-dabeere ma gosipụta na ogologo na cmc, nke na-abawanye na ogologo gemini na-enwe ogologo na-enweghị oke ọchịchọ ijikọta ọnụ.
Faustino et al. Kọrọ usoro nke agwakọta micelles nke otuonic Gemini Soursants dabere na cystine. A na-ejikwa Gemini na-ejikọ ya na ndị ọzọ na-enwetara nzukọ nke nzukọ (C 8 cys). A kọrọ na CMC ụkpụrụ nke igwe nri lipid-leactant dị ala karịa nke ndị dị ọcha. Gemini Surfractants na 1,2-glycery-3-Phospholine, mmiri - na-agbanye, micple-na-akpụ akpụ phospholipid, nwere cmc na akwara.
Shrestha na Aramaki nyochalitere nke ikpuru viscoelic - dị ka micless na sonoc-daonic-sensic surfactants na enweghị nnu na-adịghị mma. N'ime ọmụmụ a, a hụrụ n-dodicyl glutamate ka ọ bụrụ okpomọkụ dị elu na-adị elu; Agbanyeghị, mgbe a na-ewepụ ya na amino acid L-Lysine, o mepụtara micless na ihe ngwọta malitere ime dị ka mmiri mmiri ọhụụ na 25 Celsius.
6.2 ezigbo mmiri solubility
Ezigbo mmiri na-enye ngụgụ nke AAS bụ n'ihi ọnụnọ nke AS-NH. Nke a na-eme ka AAS biodegradeble na gburugburu ebe obibi karịa nke kwekọrọ na ya. Mmiri na-agbasa mmiri nke n-acyl-l-glutamic acid dị mma n'ihi otu abụọ nke carkslọ nchekwa nke abụọ. Mmiri na-esochi nke CN (ca) dị mma maka na enwere otu ihe dị iche iche nke Ionic na 1 moliel, nke na-arụpụta ihe dị irè na cell interface na cellfration na-enwe nsogbu.
6.3 krafft okpomọkụ na krafft Point
Enwere ike ịghọta ọnọdụ nke KRAFFT dị ka usoro ngere nke Sustocted nke Surraicts ha solublity na-abawanye karịa otu okpomọkụ. Ionic sfịk nwere ọchịchọ ịwapụta nri mmiri siri ike, nke nwere ike ịmalite mmiri. Na otu okpomọkụ (nke a na-akpọ krafft okpomọkụ), mmụba dị egwu ma na-enwe mmụba na solubalints na-ahụkarị. KARFT Couple nke ionic Surctactant bụ okpomoku ya na cmc.
A na-ahụkarị njirisi ngụgụ a maka ionic Surractants ma enwere ike ịkọwa ya dị ka onye na-esote: A na-ekwupụta na-enweghị isi na ọnọdụ nke KRAFFT ruo mgbe ekwesịrị na-eji nwayọọ nwayọọ na-abawanye n'ihi ogo Micle. Iji hụ na sodublity zuru ezu, ọ dị mkpa ịkwadebe mmebe ahụ na ọnọdụ okpomọkụ karịa isi obodo.
A mụụrụ Krafft nke AAS ma e jiri ya tụnyere nke na-asa ahụ Surtactants.Shrestha na Aramaki na-amụ ihe dị ka ihe ngosi (Ohta et) nke N-Hexadecanoyl AAS ma kwurịtara mmekọrịta dị n'etiti CAINFT okpomọkụ ha.
Na nnwale ahụ, a chọpụtara na okpomoku nke n-hexadecanoyl aas mụbara na ebe a na-ebelata nke ndọtị Acid (ma ewezuga Glyline na Phensylalanine). E kwubiri na na ma aluni na phenylalanine, mmekorita DL siri ike karịa mmekọrịta LL na usoro siri ike nke n-hexadecanoyl aas nnu nnu.
Brito et al. Kpebisiri ike na kainords nke Amino acid-dakọtara na-eji microcalorimetry na-eji Microcalorimetry Matfrimetry ma hụ na-agbanwe ihe dị ukwuu na ọnọdụ nke KRADFT (dị ka 47 Celsius C ka 53 Celsius. Ọnụnọ nke cis-okpukpu abụọ na enweghị ihe na-adị ugbu a na ogologo ntanye ogologo na-ebute oke na okpomọkụ. A kọrọ na n-dodicyl glutamate ka a kọrọ na okpomọkụ Krafft dị elu. Agbanyeghị, a na-eji ihe mgbochi Amino acid L-Lysine rụpụtara na usoro micless na ngwọta nke na-eme atụmatụ dị ka mmiri Newtonian na 25 Celsius C.
6.4 Ọnọdụ Ọnọdụ
Akụkụ esemokwu dị n'elu nke Surfactants bụ ihe metụtara ogologo ya nke akụkụ hydrophobic. Zhang et al. Kpebisiri ike dị elu dị elu nke sodium cocoyl glycunate site na usoro Wilhelmy (25 ±) na-ekpebi oke esemokwu na CMC dị ka 0,21 mmol-l -1. Yoshimur et al. Kpebisiri ike elu elu nke 2c n cys pydị amino acid dabere na ndị ọrụ na-arụ ọrụ nke abụọ. Achọpụtara ya na esemokwu dị na cmc belatara na ịba ụba ogologo (ruo mgbe n = 8), ebe a na-atụgharị usoro maka oghere na n = 12 ma ọ bụ ogologo.
Mmetụta nke CAC1 2 na elu esemokwu nke dicarboxylent Amino am am am am am am am. N'ime ọmụmụ ihe ndị a, a na-agbakwunye CAC1 2 nke Amino Amino aminocy pickings (c12 Malna 2, C12 Aspna 2, na c12 Gluna 2). E ji ya tụnyere plateau ma e jiri ya tụnyere cmc ma achọpụtara ya na esemokwu dị ala belata na cAC1 2 Ile anya. Nke a bụ n'ihi mmetụta nke calcium eons na nhazi nke sọks-mmiri. Elu elu nke nnu nke n-dodecylatate, n'aka nke ọzọ, ọ fọrọ nke nta ka ọ bụrụ ihe ruru 10 mmol-l -1 cAC1 2 cAC1 2 cAC1 2 cAC1 2 Ileta. N'elu 10 mmol-l -1, elu ahụ na-abawanye nke ọma, n'ihi nguzobe nke nsị nke nnu na-acha uhie uhie. N'ihi na Dodidium nnu glutamate, mgbakwunye na cAC1 2 nke mere na mbelata nke ukwuu na esemokwu dị n'elu, ebe ị gara n'ihu na-abawanye na CAC1 2 Nta na-agaghị akpata mgbanwe dị mkpa.
Iji chọpụta na onye na-ezighị ezi korini-pịdị AAS na interface mmiri, na-agbanwe agbanwe iji usoro nrụgide afụ. Nsonaazụ gosiri na maka oge ule kachasị ogologo, nke 2c 12 cys dị egwu na-agbanwe agbanwe agbanwebeghị. Ebe mbelata nke agbamume dị arọ na-adabere naanị na ịta, ogologo nke ọdụ hydrophobic, na ọnụ ọgụgụ nke ọdụ hydrophobic. Mgbe ịbawanye ihu nke sọks, na-ebelata ogologo ogologo yana ọnụ ọgụgụ nke agbụ na-ebute ngwa ire ngwa ngwa. Nsonaazụ enwetara maka ịdị elu nke c n cys (n = 8 ruo 12) ka a na-ahụkarị γc cmc na-eji usoro Wilhelmy.
N'ọmụmụ ihe ọzọ, a na-agbanwe agbanwe nke sodium ditueryl cystine (sdlc) na-ekpebi usoro sọks, na mgbakwunye, a na-ekpebi usoro olu ha site na usoro olu ha. Ihe ndị ọzọ na-eme ka a mata mmeghachi omume nke agbụ. Ihe mgbakwunye MerCactol ruo 0.1 mmol-l -1sdcc ngwọta na-eduga n'ike n'ike n'ike site na 34 mn -1 ruo 53 mn-m -1. Ebe ọ bụ na Naclo nwere ikexhilize agbụ nke SDLC na Sulfonic Otu dị iche iche, a na-ahụ na ọ nweghị ihe a na-eme mgbe naclo (5 mmọl-l-l-l-l-l-l -1 sdlc ngwọta. Nkwekọrịta na-ekpo ọkụ na-arụ ọrụ na-agbasasị na-agbasasịpụta nsonaazụ gosiri na ọ nweghị ihe eji eme ihe na ngwọta ya. A hụrụ na esemokwu dị elu SDLC ka ọ na-abawanye site na 34 m -1 ruo 60 mn -1 n'ime oge 20 min.
Ntinye ọnụọgụ abụọ
Na ndụ science, ọtụtụ otu amụbala ihe ndị na-eme vibrational AAS (Diacyllycents Surges na gas-mmiri na-eme ka nsogbu a dị mma na-akpata nsogbu electrostatic.
Njirimara 6.6 Njirimara
A na-ejikarị ndị na-agbasa ọkụ nke Amino amino na gemini sụfractants na injesations dị n'elu cmc, na-ekwenye ekwenye n'ụzọ pụtara ìhè DHRyodynamic DH (= 2r H). Ndị na-ahụ maka C N T NY na 2cn cys na-abụ nnukwu buru ibu ma nwee nkesa sara mbara ma e jiri ya tụnyere ndị ọzọ. All suskacrants niile ewezuga cys 12 nke na-etolite mkpokọta ihe dị ka 10 nm. Miclele nha nke gemini sooractacts na-ebu ibu karịa nke ndị na-ahụ maka ibe ha. Mmụba na ogologo hydrocarbon ogologo na-edugakwa mmụba na ogo micletle. ohta et al. Kọwaa ihe nchịkọta nke ndị na-eme ihe atọ dị iche iche nke n-dodecyl-pheshy-alanine tetrametylamethylamethylamethylamethylamethylametylametylamimers na ndị na-ahụ maka ihe dị oke mkpa na ntinye uche na ngwọta. Iwahashi et al. na-enyocha site na okirikiri dichroism, nmr na vepo nrụgide acid-l-glutamic acid, n-dodecanoyl acid-l-glutamil, acetonitrile, 1,4-Dioxorotane) na Njirimara na-enyocha ihe ndị na-emegharị mmiri site na okirikiri dichos, nmr na vepo nrụgide nke Osmometry.
6.7 interfaciall Admiction
Mgbasa ozi nke Amino acidption nke Amino acid-dabeere na ya na ndị otu ya na ndị otu ya bụ otu n'ime usoro nyocha. Iji maa atụ, njikọta nke Desmụaka Docorpl nke Demomatic Aromatic Audic Acids nwetara site na ka ọ na-enyocha ya na Lep. Nsonaazụ gosiri na ọ na-egosiputa ebe dị ala na-enwekarị nsogbu na mmiri mmiri na mmiri / hexane interface, n'otu n'otu.
Bordes et al. Nyochaa omume na usoro mgbasa ozi nke Amino Amino acid na-acha uhie uhie, dodinomalonate (na na atọ, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2). Dabere na akụkọ a, cmc nke ihe dị omimi dị omimi bụ 4-5 ugboro dị elu karịa nke monacarboxyyylated dodine glycine nnu. A mara nke a na nguzobe nke abrogen n'etiti dicarboxants na ụmụ irighiri ihe site na ndị dị nso site na ndị dị n'etiti ndị dị na ya.
6.8 usoro omume
A na-ahụ usoro nke usoro cubic na-enweghị isi nke ọma maka ndị na-elekọta ihe dị oke egwu. Molecules nwere nnukwu isi otu na-etolite ngwakọta nke obere urvature. Marques et al. na-amụ usoro omume nke 12YS12 / 12SERS na 8YERS8 / 16SER8 usoro na-egosi mgbanwe mpaghara na-aga n'ihu na mpaghara nke mictalle na mpaghara micellar mpaghara vesicle mpaghara). Ọ ga-ahụ na maka mpaghara Vesiclecle nke 12YS12 / 12SEr sistemụ na-ejikọ ya na mickes, ebe usoro Vesicles nwere naanị usoro.
Mixtuds na-agwakọta nke Lisine- na Surre-Dabere na Sour-Dabere: 12smetric 12lys12 / 12smetric (n'aka ekpe) na asythmetric 8/2
6.9 Ike Ike
Kochii et al. Nyochaa ikike mgbochi, esemokwu, na 3-dodecyl-2-dodecyl-2-dodlecyyl] -l-Argentinine], na AAS ndị ọzọ. Tụnyere ya na sọlfọ (hatphoteric na amphotocts), nsonaazụ gosiri na aas nwere ike ike na-enwe ike karịa na sustoral Surfters.
BACZKO et al. Synic Amino Acid Amino Acid Sourt Sourt ma nyochaa ha uwe dị ka usoro ngbanwe chiral. A series of sulfonate-based amphiphilic L-Phe or L-Ala derivatives with different hydrophobic tails (pentyl~tetradecyl) were synthesized by reacting amino acids with o-sulfobenzoic anhydride. Wu et al. Syythhesis Sinds nke N-BATY ASAS naNyochaa ikike emulsion ha na emulsions mmiri, na nsonaazụ a na-egosipụta nke ọma na etyl acetate dị ka oghere mmanụ karịa n-hexane dị ka mmanụ.
6.10 Ọganihu na Sonsonisis na Mmepụta
Enwere ike ịghọta nguzosi mmiri siri ike dịka ike nke surfacted iji guzogide ọnụnọ nke eonsdị calcium na mmiri siri ike, ya bụ, ikike ịzere oke ikuku. Ndị nwere nnukwu nguzogide mmiri siri ike bara ezigbo uru maka usoro na ngwaahịa nlekọta na-akpata ya. Enwere ike inyocha nguzo mmiri siri ike site na-agbakọ mgbanwe na soldọ elu na elu ọrụ nke sọks calcium n'anya ọnụnọ.
Wayzọ ọzọ ị ga - esi na - eguzogide mmiri siri ike bụ ịgbakọ pasent ma ọ bụ grams nke sọks chọrọ site na 100 g nke sonium Oheree ka a chụsasịa na mmiri. N'ebe dịgasị elu nwere nnukwu mmiri siri ike, dị elu nke calcium na magnesium eons na minesium nwere ike ime ụfọdụ ngwa ndị siri ike. A na-ejikarị sodium ion dị ka counter ion nke soncitic soft. Ebe ọ bụ na ion calcium ion ga-agharịrị abụọ solocacles, ọ na-eme ka sọsọ na-aga n'ihu iji kpochapụ ngwa ngwa site na ime ihe na-enweghị isi.
Ọmụmụ ihe siri ike nke Eas gosipụtara na ndị otu na-ahụkarị na-eguzosi ike na-eguzogide ya, na ebili mmiri na-emetụta ọnụ ọgụgụ ndị otu oghere dị n'etiti ìgwè abụọ nke ozu abụọ. Usoro nke acid na ike mmiri guzogide bụ c 12 glycine <c 12 aspartate <c 12 glutamate. Tụnyere ihe nkekọ dicarxylexylexy na dicarxy na diinoxy sara mbara, na -acha ya na ihe dị elu nke ikpeazụ a na-abawanye na mgbakwunye nke acid. Acid n-alkyl amino gosipụtara mmetụta na-ekwupụta na ọnụnọ calcium, na c 12 aspartete guzobere gel. C 12 glutamate gosipụtara ọrụ dị elu na elu c 2+ ịta ma na-atụ anya na a ga-eji ya na oke mmiri.
6.11 Sụpụta
Sụgharịa na-ezo aka ike nke sọfcences iji gbochie mkpọsa na ndọpa esi na ngwọta.Mgbasawanye bụ ihe dị mkpa nke ndị na-eme Surractants na-eme ka ha dị ọcha maka iji ihe na-ekiri, ihe ịchọ mma na ọgwụ.Onye na-achụpụ onwe ya ga-enwerịrị ihe a na-eme, Ether, Amino ma ọ bụ Amino n'etiti otu hydrophobic otu na ọnụnọ hydrophilic otu (ma ọ bụ n'etiti otu hydrophobic otu).
N'ozuzu, anionic soroctants dị ka alkanolamido sọlfọ na ndị amphosic sororactants dị ka amidosulfobetine na-adịkarị ike dịka ndị nnọchi anya calcium dị irè.
Ọtụtụ mgbalị na-eme ka a chụọ ihe a chụọ, ebe N-Lauroyl Lysine ga-ekwekọrịta na mmiri ma sie ike iji maka usoro ịchọ mma.Na usoro a, n-acyl-acid acids nke kacha mma na-agbasa ma na-eji ụlọ ọrụ ịchọ mma iji meziwanye usoro.
07 na-egbu egbu
Ndị na-eme mkpọtụ, ọkachasị sọlfọ na-acha uhie uhie, na-egbu egbu mara mma. Ngwurugwu ha buru oke ibu n'ihi ihe nlere nke mgbasa ozi-ion mmekorita nke Surfactants na mmiri mmiri. Ibelata cmc nke susc nke na-edugakarị na mgbasa ozi siri ike nke Surractions, nke na-ebutekarị ha oke oke mma. Mmụba n'ogologo nke hydrophobic yir Surfactants na-edugakwa mmụba na-adịghị mma.Kasị anya AAS dị ala ma ọ bụ ihe na-adịghị mma ma ọ bụ na gburugburu ebe obibi (ọkachasị maka ihe omimirinism) ma dịkwa mma maka iji dị ka nri na ihe ịchọ mma.Ọtụtụ ndị na-eme nchọpụta egosipụtawo na amino acid Sourfters bụ nwayọ na enweghị mgbakasị ahụ na anụ ahụ. A maara ndị na-ahụ maka ndị dabere na ihe na-enweghị ihe na-enweghị ihe na-adịghị mma karịa ndị na-ahụ maka ndị otu ha.
Brito et al. Na-amụ akwụkwọ amamihe na ihe na-egbu egbu nke Amino amppological nke Amino ampociile na [e debere ya, serine (mgbaze)] Ha na-ejikọ sinsicles nke dodecytlethyrlttethylamtyyrtrium bromide (dtab) / ma ọ bụ mixenic na agwakọta nke hemovytics, na-egosi na ha na-egbu egbu na-enweghị ihe na-egbu egbu karịa ihe na-enweghị atụ.
Rosa et al. Nyochaa njikọta (mkpakọrịta) nke DNA ka ọ bụrụ onyinye mara mma Amino acid. N'adịghị ka ndị na-enweghị atụ, nke na-apụtakarị ịbụ ihe na-egbu egbu, mmekọrịta nke sedic acid Soursents dị ka ọ bụghị ihe na-enweghị nsi. The contic AAS sitere na Argentinine, nke na-eme ka vesicles vesicles stable na ngwakọta ụfọdụ sonic soft. A na-akọkwara corrodom na-egbochi Amino amino amino am acid ka ọ bụrụ ihe na-enweghị nsi. A na-eji ịdị ọcha ndị a na-adị mfe. Ọtụtụ ọmụmụ ihe egosila na sọlfọ acid na-acha uhie uhie dị elu dị elu na mgbochi mgbochi corrosion.
Na nnyocha na-adịbeghị anya, perinellit et al. Kọrọ profaịlụ na-eju afọ nke rhamnolipids tụnyere ndị na-asa ahụ. A maara Rhamnolpids na-eme ihe dị ka ndị ọzọ na-eme ka mmadụ nwee ike. Ha kọkwara mmetụta nke rhamnolipids na epithelial permeability nke ọgwụ Macromecular.
08 antimicrobial na-arụ ọrụ
Enwere ike ịtụle ọrụ antimicrobial nke sustoctants site na itinye uche na-egbochi. Agụla antimicrobial arụ ọrụ nke ndị dabere na ihe ndị dabeere na ihe zuru ezu. Achọtara nje nje Gram-na-adịghị mma ka ọ bụrụ ihe na-eguzogide na-eguzogide ndị na-eme ihe na-adabere na argeria na-erughị afọ gram. A na-enwekarị ọrịa antimicrobial na-abawanye site na ọnụnọ nke hydroxyl, cylopropane ma ọ bụ nke agbụ na-enweghị mgbochi ma ọ bụ nke agbụ na-enweghị acy. Castillo et al. gosiri na ogologo nke acy acy na ezigbo ụgwọ kpebiri uru HLB (nguzozi Lrodhilic-Lorphilic) nke moleku, ma ndị a na-enwe mmetụta na ikike ha na-emebi emebi. Nα-acylargine methy Esta bụ klas ọzọ dị mkpa nke scroctants councrations na-arụ ọrụ na-arụ ọrụ ma ọ dị obere ma ọ bụ enweghị oke ọkpọ. Ọmụmụ ihe na - eme na Methyl na Methyl Ester Ester-3-Propyltioxyl-3-Phosprioxyl-3-Phosltrioxyl na ọnụnọ nke ihe ndị a na-eji emepụta ihe ngosi Ndị na-eme ihe na-enwe ezigbo antimicrobial na-egosi na ndị na-ahụ maka sustocts nwere ezigbo antibacterial.
Njirimara 09
Njirimara Njirimara nke Sustologits Na-arụ ọrụ dị oke mkpa na-ekpebi na ịkọ nkọ na-ekpebi na ọrụ dị iche iche, gụnyere nri ọgwụ, mmịpụta mmanụ, nlekọta nke onwe gị na ngwaahịa nlekọta onwe onye. E duziela ọtụtụ ọmụmụ na-atụle mmekọrịta dị n'etiti Viscoelastice nke amino acid Sours na cmc.
10 Ngwa na ụlọ ọrụ ịchọ mma
A na-eji AAS na usoro nke ọtụtụ ngwaahịa nlekọta onwe onye.A na-achọpụta na potassium n-copoyl glycinate dị nro ma ejiri ya mee ihe na ihu dị ọcha iji wepu sludge na etemeete. n-acyl-l-glutamic nwere udiri ifuru abuo, nke na eme ka o sikwuo mmiri. Otu n'ime Aas, AAS sitere na c iri na abụọ acids acids a na-eji ọtụtụ ebe na ihu ihu iji wepu sludge na etemeete. A na-eji AAS na 18 yinye dị ka emulsians na ngwaahịa nlekọta anụ ahụ, a na-ama nnupụta nnu na-enweghị nkụda mmụọ na-enweghị ike iji ya mee ihe na-enweghị isi na ngwaahịa nlekọta nwa. AASEIGL-siteres apas eji na-eme eze ezé nwere ezigbo ihe mgbochi dị ka ncha na enzyme na-egbochi arụmọrụ.
N'ime afọ iri ole na ole gara aga, nhọrọ nke surfactants maka ihe ịchọ mma, ngwaahịa na ọgwụ na-elekwasị anya na oke mma, ịdị nwayọọ, ịdị nwayọ na mmetụ na nchekwa. Ndị na-azụ ahịa nke ngwaahịa ndị a na-ahụkarị nke iwe, oke mma na gburugburu ebe obibi.
Taa, a na-eji AAS mepụtara ọtụtụ Shampooos, ntutu dị ọcha na saa saa n'ihi ọtụtụ uru ha dị na kọmititi ọdịnala ha na ngwaahịa nlekọta onwe ya.Ndị na-eme protein na-enwe ihe dị mma dị mkpa maka ngwaahịa nlekọta nke onwe ya. Somefọdụ ndị AAs nwere ikike ịmepụta ihe nkiri na-eme ihe nkiri, ebe ndị ọzọ nwere ikike na-enweghị isi.
Amino acid dị mkpa na-eme moduring ihe na stratum corneum. Mgbe mkpụrụ ndụ epider nwụrụ, ha na-aghọ akụkụ nke stratum corneum na proteintel intacellular na-eji nwayọọ nwayọọ na amino acid. Ndị a amino acid a na-ebugharịkwa na stratum cornem, ebe ha na-amịpụta abụba ma ọ bụ abụba dị ka ihe na-eme ka ọ dị elu nke elu anụ ahụ. Odika 50% nke ihe na - eme ihe na - eme ihe na aru ahu bu amino acid na pyrolidone.
Clonagen, ihe a na-ahụkarị, a na-ahụkarị osisi, nwekwara amino acids na-eme ka akpụkpọ ahụ dị nro.Nsogbu akpụkpọ dị ka ike na dullness bụ n'ihi nnukwu akụkụ na enweghị amino acid. Otu nnyocha gosiri na ịgwakọta amino acid na mmanu mmanu mmanu mmanu oku, ebe ndi ahu metuta alaghachi na steeti ha n'enweghi oria.
Achọpụtakwala amino acid na-aba uru na ilekọta cutticles mebiri emebi.Ntutu ntutu, adighi-egosi na ntutu di iche iche nwere ike igosi mbelata nke amino acid corned cornem cornem. Amino acid nwere ikike ịbanye na ya nke ọma n'ime ntutu isi ma na-enwe ike site na anụahụ.Ike a nke amino acid dabere na-eme ka ha baa uru na shampoos, ntutu isi, na ọnụnọ ntutu, na ọnụnọ Amino na-eme ka ntutu sie ntutu ike.
11 Ngwa na Cosmetics kwa ụbọchị
Ugbu a, enwere usoro na-eto eto Amino acid nke dabere na-adịgide adịgide n'ụwa niile.A maara AAS nwere ike nhicha dị ọcha, ike na-acha na akwa dị nro, nke na-eme ka ọ dị mma maka ihe ndị dịịrị ụlọ, shampoos, ahụ na-ehicha ahụ na ngwa ndị ọzọ.A na-akọ akụkọ ASPOTIC AASA ka a kọrọ na ọ bụ ihe dị irè dị mma na Njirimara Njirimara. Achọtara iji ihe ndị na-egbochi ihe nke n-alkyl-β-alcylyly na-eji belata iwe anụ ahụ. A na-akọ akụkọ mmiri mmiri nke mejupụtara n-kom-cocopropie na-atọ ụtọ ka ọ bụrụ ihe na-adịghị mma maka mmanụ dị na mbara igwe. Egosiputala ihe nkiri Aminocarylic, C 14 COSCH 2 NHCH 2 na-eme ka ọ dị mma na-ehicha ma si otú a na-akwụ ụgwọ iji belata.
Nkwadebe nke ihe mgbochi na-adabere na N- (n 'ogologo-layl) na Tatsui na Tattuya ka mma, ụfụfụ dị mma na-agbaji. Kao zulitere usoro na-egbochi ihe dabere na n-acyl-1-acdroxy-β-lanine ma kọrọ isi mgbakasị ahụ, dị elu na ike mwepụ dị elu.
Companylọ ọrụ Japanese Ajanomoto na-eji obere ihe na-egbuke egbu egbu ma na-adị mfe nsị, l-glutamine na L-LYSINIE na shampEtics (ọgụgụ nke 13). Ike nke ihe mgbakwunye enzyme na usoro a na-eme ka iwepu protein protein. N-ACLYL AAS sitere na acid acid, alanine, methyylycine, a kọọpụtara na aspatic acid maka ojiji ndị dị mma. Ndị a na-asa ahụ na-adịghị amụba viscosity ma ọlị, ọbụlagodi obere okpomọkụ, enwere ike ibufe arịa dị mfe site na nchekwa nke ngwaọrụ ụfụ iji nweta ụfụfụ.
Oge post: Jun-09-2022